Book excerpt: In this book, the authors gather and present topical research in the study of statistical mechanics and random walk principles and applications. Topics discussed in this compilation include the application of stochastic approaches to modelling suspension flow in porous media; subordinated Gaussian processes; random walk models in biophysical science; non-equilibrium dynamics and diffusion processes; global random walk algorithm for diffusion processes and application of random walks for the analysis of graphs, musical composition and language phylogeny.