Book excerpt: The ~1 Myr history of the Purico-Chascon volcanic complex (PCVC) records significant changes in the production and storage of magmas in the crust. At ~1 Ma activity at the PCVC initiated with the eruption of a large 80-100 km3 crystal-rich dacite ignimbrite with restricted whole rock 87Sr/86Sr isotope ratios between 0.7085-0.7090. In-situ analyses of plagioclase from the Purico ignimbrite have 87Sr/86Sr=0.7087-0.7090. The dacite magma accumulated and evolved at relatively low temperatures around 800-850 °C in the upper crust at 4-8 km depth. Minor andesite and rhyolite pumice late in the sequence have similar restricted whole rock 87Sr/86Sr=0.7089-0.7091. The radiogenic isotopes of this 0.98 Ma activity are consistent with all these compositions resulting from 50 to 70% crustal assimilation by parental Central Andean "baseline" magmas at depths between 15-30 km. The final eruptions at the PCVC occurred 0.18 Ma producing three small 5 km3 crystal-rich dacite lava domes with whole rock 87Sr/86Sr ratios 0.7075 to 0.7081 containing abundant basaltic-andesite enclaves with whole rock 87Sr/86Sr ratios of 0.7057- 0.7061. Plagioclase and amphibole from samples from the largest of these domes, Cerro Chascon, record two distinct magmatic environments; an upper crustal environment identical to the Purico ignimbrite and a second deeper, ~15-20 km depth, higher temperature (~922-1001 °C) environment consistent with conditions recorded in the basaltic andesite enclaves. Accordingly, plagioclase cores in the host dacite lava and enclaves have enriched in-situ 87Sr/86Sr isotopic compositions of 0.7083 to 0.7095 while plagioclase rims and microphenocrysts in the enclaves have 87Sr/86Sr isotope ratios from 0.7057 to 0.7065 and 0.7062 to 0.7064 respectively. Lavas from Cerro Chascon also contain abundant Fo82 olivine with spinel and basaltic melt inclusions that crystallized in a deep crustal environment (1250 °C) consistent with a lower crustal MASH zone. The high baseline isotopic ratios observed in bulk rock and plagioclase crystals from Cerro Chascon (0.7057-0.7065) are consistent with MASH processes. The evolution of the PCVC is a microcosm of the Andean arc in this region where, from 10 - 1 Ma, dominantly dacitic upper crustal magmatism of the Altiplano-Puna Volcanic Complex ignimbrite flare-up persisted until ~1 Ma, when smaller volume, more heterogeneous and less isotopically enriched basaltic andesite to dacite composite volcanoes signal a return to steady state arc volcanism. I suggest that the PCVC captures the transition of the Andean arc from flare-up to steady state. The temporal trend at the PCVC is consistent with a waning thermal flux. High magmatic fluxes during the flare-up would have resulted in elevated geothermal gradients and efficient crustal processing leading to a dominantly dacitic upper crust (0 to 35 km) that fed the large volume Purico ignimbrite. As magmatic flux and thermal energy wanes, crustal isotherms relax resulting in greater thermal contrast between parental magmas, crust and remnant upper crustal dacite magma. This manifests in more heterogeneity and the survival of less isotopically enriched magmas in the upper crust. These arc scale magma dynamics are recorded even at the intra-crystalline scale. Individual crystals from Cerro Chascon also record vital information on the crystallization and evolution of mantle-derived magmas in continental magmatic arcs. Fo2 olivine, olivine hosted spinel, and basaltic melt inclusions record the crystallization of olivine at1250 °C in conditions consistent with a lower crustal (~70 km depth) MASH zone. Another significant crystallization event appears to have occurred at ~20 km depth, characterized by the crystallization of high An plagioclase (An--24) at ~1100-1050 °C followed by high-Al amphibole (~12-15 wt.% Al2O3) at ~1000-950 °C. The appearance of amphibole on the liquidus appears to have resulted from a nearly 2-fold increase in melt water content following ~45% crystallization of high An plagioclase. Following this extensive crystallization the highly crystalline mafic magma ascended into the upper crust and interacted with the remnant crystal mush from the Purico ignimbrite magma reservoir. Low An plagioclase (An3955), low Al amphibole (~6-9 wt.% Al2O3), sanidine, and biotite retain the chemical composition of the Purico ignimbrite magma, whereas, olivine, high An plagioclase, and high Al amphibole record the mafic recharge magma. The textures and compositions observed in Cerro Chascon are common in both continental and oceanic magmatic arcs worldwide and I propose that multiple crystallization events and upper crustal assimilation are fundamental processes intrinsic to arc magmatism. I have also used in situ 87Sr/86Sr isotope ratios in plagioclase from andesite, dacite, and rhyolite pumice from the ~1 Ma Purico ignimbrite to determine the cause for compositional zoning in the Purico ignimbrite magma reservoir. Andesite pumice contains two texturally, compositionally, and isotopically distinct types of plagioclase, small (500 [micro]m) subhedral to euhedral crystals with high MgO (130-490 ppm) and low 87Sr/86r crystals (0.7076-0.7084) record a hot (900 °C) andesite magma derived from an ~20 km deep magma reservoir. In contrast, the second type of plagioclase in the andesite appear to broken fragments of larger crystals and have significantly lower MgO (90-240 ppm), higher 87Sr/86Sr (0.7096-0.7114), and appears to be derived from the lower temperature (crystallized at ~800-900 °C), upper crustal (10 km) plutonic basement. Dacite pumice also contains two texturally and compositionally distinct types of plagioclase. However, both types have very restricted MgO (b.d.l.-200 ppm) and 87Sr/86Sr (0.7085-0.7095) ratios and appear to have grown at ~850°C. These crystals are also significantly larger (1000 [micro]m) than plagioclase from the andesite pumice and have clear euhedral rims. Rhyolite pumice from the Purico ignimbrite also contains distinct types of plagioclase. Both types of plagioclase are similar in size (