Book excerpt: This book highlights novel research work done on cold atom-based quantum networks. Given that one of the main challenges in building the quantum network is the limited entanglement distribution distance, this book presents some state-of-the-art experiments in tackling this challenge and, for the first time, establishes entanglement between quantum memories via metropolitan-scale fiber transmission. This achievement is accomplished by cooperating high-efficiency cold quantum memories, low-loss quantum frequency conversion modules, and long-fiber phase-locking techniques. In the book, the scheme design, experimental setup, data analyses, and numerous technical details are given. Therefore, it suits a broad readership that includes all students, researchers, and technicians who work in quantum information sciences.