Book excerpt: This book provides a comprehensive overview of methanol fuel. It reviews challenges and solutions in using methanol fuel in the transportation sector. Methanol is also used as the fuel in direct methanol fuel cells (DMFCs), and thus, the book reviews their working principles, performance, challenges, solutions, and applications. It also explores new developments in anode and cathode electrocatalysts, with an emphasis on nanostructured carbon support materials and their structure, electrochemical properties, and performance.