Book excerpt: This book presents comprehensive coverage of current and emerging multiple access, random access, and waveform design techniques for 5G wireless networks and beyond. A definitive reference for researchers in these fields, the book describes recent research from academia, industry, and standardization bodies. The book is an all-encompassing treatment of these areas addressing orthogonal multiple access and waveform design, non-orthogonal multiple access (NOMA) via power, code, and other domains, and orthogonal, non-orthogonal, and grant-free random access. The book builds its foundations on state of the art research papers, measurements, and experimental results from a variety of sources.